A Sur v e y of Cr yst allin e Def ect s

O u t lin e Def ect s

0 D D ef ect s

V acanc i es & I n t er st i t i a l s

1 D De f e c ts ( D islo c a tio n s )

2 D D ef ect s

G r a i n & t w i n bounda r i e s

3 D D ef ect s

C ohe r e nt vs . i nc ohe r e nt

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inc lus ions , p re c ipi ta te s

S i ngl e c r y s t a l o f Mn S , spa c e gr o up Fm 3 m , F C C c r y s t a l s tru c tu r e

Cr yst allin e S o lid s

h t tp: / / w w w . w e be l e m e n ts .c o m / c a l c i um / c r y s t a l _ s t r uc t ur e .h tm l

Pe ri odi c , l ong - ra nge orde re d st ruc t ure s

calcium crystal structure image (space filling style)
http://www.mike-short.com/Science/PeriodicTable/Ca.jpg

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F a ce ce n t e r e d cu b i c c a l ci u m cr y s t a l s t r u ct u r e

S i n g l e cr y s t a l s o f c a l ci u m m e t a l u n d e r k e r o s e n e

For m Fol l ows S tr uc tur e

h t tp: / / w w w .zk g .de / e n/ a r ti k e l / bi l dpo pup_ e n_ 1698578.h tm l ? i m a g e = 5

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P y r i t e ( F eS 2 ) , s i m pl e

G o l d ( Au) , f a ce cen t er e d reserved.

cubi c ( F CC) G y p s um , m o no cl i ni c

cubi c ( S C) h t tp: / / w w w .pa l a m i ne r a l s .c o m h t t p :/ / w w w . g a lle r ie s . c o m / m in e r a ls / W i k i med i a C o mmo n s / ne w s _ 2007_ v 2.php s y m m e tr y / m o no c l i n.h tm

G r ain vs. Cr yst al St r u ct u r e

W hy do gra i ns l ook m ore sphe ri c a l , w he n c ryst a l

cr y s t a l s t r u ct u r e (l e f t ), m i cr o g r a p h

o f F e - 12Cr - 2 S i (r i g h t )

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G r ain vs. Cr yst al St r u ct u r e

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{ 1 1 1 }

{ 0 0 1 }

Wu l f f c r y s ta ls d e s c r ib e

l o wes t en er g y s u r f aces

E xposi ng cl o s e p a cked pl ane s l ow e rs s urfa c e en er g y

This image is in the public domain.

h t tp: / / w w w .c t c m s .ni s t . g o v / w ul f f m a n/ e x a m pl e s .h tm l

G r ain vs. Cr yst al St r u ct u r e

W e s ee 2 D s l i ces o f Wu l f f c ryst a l s a s gra i ns!

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h t tp: / / w w w .c t c m s .ni s t . g o v / w ul f f m a n/ e x a m pl e s .h tm l

P o in t Def ect s ( 0D) V acan cies

W as , p . 1 6 3

[ Was, Gary S. Fundamentals of Radiation Materials Science , p. 163. ISBN: 9783540494713.] removed due to copyright restrictions.

P o in t Def ect s ( 0D) M u lt ip le V acan cies

W as , p . 1 6 3

[ Was, Gary S. Fundamentals of Radiation Materials Science , p. 163. ISBN: 9783540494713.] removed due to copyright restrictions.

P o in t Def ect s ( 0D) In t er st it ials

E x tr a a to m s sh o v e d in to th e c r y s ta l la ttic e

W a s , p . 157

O ct a h ed r o n

T e t r a he dr o n

Oc t a h e d r a l in t e r s titia l in B C C T e tr a h e d r a l in t e r s titia l in B C C la t tic e la t tic e

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P o in t Def ect s ( 0D) S p lit In t er st it ials

W a s , p . 159

D um bbe l l s a re oft e n l ow e r e ne r gy c onfi gura t i ons

A l so m uc h e a s i e r t o di f fuse

O ne i nt e r s t i t i a l c a n knoc k” t he ot he r in t he ir c o m m on di re c tion

L ow e r di s t a nc e t o m ove m e nt

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P o in t Def ect E n er g ies

W a s , p . 160

Ha r d e r t o m a k e , e a s i e r t o m ov e

E a s i e r t o m a k e , h a r d e r t o m ov e

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P o in t Def ect E n er g et ics

H ow m uc h e ne r gy t o m ak e a v acan cy ?

R e mo v e an a t o m b y br ea k i ng bo nds ( + )

L e t o th e r a t o m s re l a x i n w a rd ( - )

P o in t Def ect E n er g et ics

H ow m uc h e ne r gy t o m a ke a v a c a n c y ?

Fe - Fe bond di s s oc i a t i on e ne r gy:

R e mo v e an a t o m b y b r e ak i n g b o n d s ( + )

118 𝑘𝐽

𝑚 𝑜𝑙

= 1 . 22𝑒 𝑉 [1 ]

Fe - F e cl u st er cal cu l at i o n s g i v e 0. 64e V [ 2]

Z= 8 i n B C C Fe : 5 . 12 9 . 76𝑒 𝑉

[1 ] Y - R Luo. B ond D i s s oc i at i on E ner g i es . C R C H andbo o k ( 2009)

[2 ] T . N ak az aw a , T . Ig a r a s h i , T . Ts u r u , Y . K a ji , C om p. M at er . S c i . , 46( 2) : 36 7 - 375 ( 2009)

P o in t Def ect E n er g et ics

Z=8 i n BCC F e:

5. 12 2 9. 76 1 𝑒𝑉

M ol e c ul a r dyna m i c s (M D ) c a lc u la tio n s [ 3 ] s h o w :

𝐸 𝑉 𝑎 𝑐 𝑎 𝑛 𝑐 𝑦 = 1. 83𝑒 𝑉

D i f fe re nc e due t o c rys t a l r el ax at i o n

L e t o th e r a t o m s r e l a x i n wa r d ( - )

[1 ] Y - R Luo. B ond D i s s oc i at i on E ner g i es . C R C H andbo o k ( 2009)

[2 ] T . N ak az aw a , T . Ig a r a s h i , T . Ts u r u , Y . K a ji , C om p. M at er . S c i . , 46( 2) : 36 7 - 375 ( 2009)

[3 ] B . D . W i r th e t a l . J. Nu c l . M a te r . , 244: 18 5: 1 9 4 ( 1997)

P o in t Def ect E n er g et ics

W h ic h in te r stitia l is m o st sta b le ?

Courtesy of Elsevier, Inc., http://www.sciencedirect.com . Used with permission. Source: Wirth, B. D., et al . " Energetics of Formation and Migration of Self-interstitials and Self-interstitial Clusters in α-iron ." Journal of Nuclear Materials 244, no. 3 (1997): 185-94.

I n t e r s titia l

D um bbel l

B . D. W i r th e t a l . J. Nu cl . M a te r . , 244: 18 5 : 1 94 ( 1997)

P o in t Def ect E n er g et ics

W h ic h in te r stitia l is m o st sta b le ?

Courtesy of Elsevier, Inc., http://www.sciencedirect.com . Used with permission. Source: Wirth, B. D., et al . " Energetics of Formation and Migration of Self-interstitials and Self-interstitial Clusters in α-iron ." Journal of Nuclear Materials 244, no. 3 (1997): 185-94.

I n t e r s titia l

D um bbel l

D o e s it m a tte r ? B . D. W i r th e t a l . J. Nu cl . M a te r . , 244: 18 5 : 1 94 ( 1997)

Dir ect M easu r em en t o f

Pos i t r on a nni hi l a t i on sp ectr o sco p y ( P A S )

S hoot pos i t r ons i nt o m a te r ia l, th e y a n n ih ila te v e r y q u ic k ly w ith lo c a l el ect r o n s

P os i t r ons c a n bi nd t o v acan c y , wh i ch h as a r ed u ced el ect r o n cl o u d

𝑒𝒆𝒆

𝐶

1𝑉

M ehr e r , p . 7 8

Me a n p o s itr o n lif e tim e in a lu m in u m

L ast s l o n g er ! © Springer. All rights reserved. This content is excluded from our Creative Commons license. For more information,

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1𝑉

Dir ect M easu r em en t o f 𝐶 𝑒𝒆𝒆

A. K h e lla f et al . , M at er . T r an s. 43( 2) : 18 6 ( 2002 )

Q u e n c h in g re s i s t a n c e m e a s u re m e n ts

Heat m at er i al t o h i g h t em p er at u r e, q u en ch , m easu r e r esi st i v i t y

R e s is tiv ity d ir e c tly pr opor t i ona l t o va c a nc y co n cen t r at i o n

M easu r ed at l i q u i d - He

t em p er at u r e R e s i s t i vi t y o f al u mi n u m v s . q u e n c h i n g t e mp e r a t u r e

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Dislo cat io n s ( 1D)

W as , p . 2 6 8

E xt ra ha l f - pl a ne of a t om s s hove d i nt o t he l a t t i c e

T w o ty p e s : E dge & S cr ew

[ Fig. 7.2 in p. 268 from Was, Gary S. Fundamentals of Radiation Materials Science , ISBN: 9783540494713 ] removed due to copyright restrictions.

Dislo cat io n s ( 1D)

W as , p . 2 6 8

E xt ra ha l f - pl a ne of a t om s s hove d i nt o t he l a t t i c e

T w o t ype s: E dge & S cr ew

[ Fig. 7. 3 in p. 268 from Was, Gary S. Fundamentals of Radiation Materials Science , ISBN: 9783540494713 ] removed due to copyright restrictions.

E d g e vs. S cr ew Dislo cat io n s

P as s c h i e r an d T r ou w , “M i c r ot e c t on i c s ,” p . 33 ( 2005)

burgers vector

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E d g e vs. S cr ew Dislo cat io n s

P as s c h i e r an d T r ou w , “M i c r ot e c t on i c s ,” p . 33 ( 2005)

B u rg e rs v e c t o rs

D islo c a t io n c o r e s

b s

b s

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The B ur ge r s V e c tor

S t ar t at o n e at o m , m ak e a c i rc l e a round t he di sl oc a t i on c ore

Th e Bu r g er s V ect o r is t he di re c t i on you m ove t o re a c h your st a rt i ng poi nt

Ex am p l e: Ed g e di sl oc .

W a s , p . 275

D islo c

c o r

D islo c a t io n c o r e lin e

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Dislo cat io n G lid e

M ove m e nt one pl a ne a t a t i m e a l ong t he s l i p d ir e c tio n

W as , p . 2 7 2

[ Fig. 7. 8 in p. 2 72 from Was, Gary S. Fundamentals of Radiation Materials Science , ISBN: 9783540494713 ] removed due to copyright restrictions.

E d g e Dislo cat io n G lid e

A video is played in class to demonstrate the concept.

h t tp: / / y o utu.be / k k 2o O x S D Q 7U

Dislo cat io n G lid e

M ove m e nt one pl a ne a t a t i m e a l ong t he s l i p d ir e c tio n

[ Fig. 7. 9 from Was, Gary S. Fundamentals of Radiation Materials Science.

ISBN: 9783540494713 ] removed due to copyright restrictions.

Dislo cat io n Clim b

V a c a nc y di f fusi on t o di s l oc a t i on c ore

W as , p . 2 7 3

V acan ci es ar e at t r act ed t o t h e co m p r essi v e st r ess at co r e

[ Fig. 7. 1 2 in p. 2 73 from Was, Gary S. Fundamentals of Radiation Materials Science , ISBN: 9783540494713 ] removed due to copyright restrictions.

Dislo cat io n Kin ks, Jo g s

A lle n , K in e tic s o f Ma t e ria ls , p . 1 1 6

D i s l oc a t i ons p re fe re nt i a l l y m ove on s l i p syst e m s

C er t ai n d i r ect i o ns o f easi er m ove m ent

C l os e p acke d p l ane s sl i p i n cl os e pa cke d d i r ect i ons

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Dislo cat io n M o t io n

W as , p . 2 7 7

[ Fig. 7. 18 in p. 2 77 from Was, Gary S. Fundamentals of Radiation Materials Science , ISBN: 9783540494713 ] removed due to copyright restrictions.

G lissile vs. S essile S ect io n s

A lle n , K in e tic s o f Ma t e ria ls , p . 1 2 4

T w o edg e di sl o c a t i o ns m o v i ng t o w a r ds ea c h o t her f o r m a se ssile j og

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D i s l oc a ti on Loops

Lo o p s h av e m i x ed ed g e/ s cr ew ch ar act er

May b e ci r cular plane s of at om s b et w een t w o p l ane s

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D i s l oc a ti on Loop S our c e s

C om e from se ss i l e s e c t i ons o f di sl oc a t i ons

O ld s t r a in d ir e c t io n

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Dislo cat io n V id eo s!

h t t p : / / w w w . n u m o d is . f r / t r id is / T E M / m e c h an is m s / m u lt ip lic a t io n . h t m l

D islo c a t io n so u r c e s in M o - 5N b

A video is played in class to demonstrate the concept.

Dislo cat io n V id eo s!

h t t p : / / w w w . n u m o d is . f r / t r id is / T E M / m e c h an is m s / m u lt ip lic a t io n . h t m l

A Fr a n k - R e a d S o u r c e in S ilic o n

A video is played in class to demonstrate the concept.

Dislo cat io n V id eo s!

h t t p : / / w w w . n u m o d is . f r / t r id is / T E M / m e c h an is m s / m u lt ip lic a t io n . h t m l

D islo c a t io n so u r c e in Ge a t hi g h t e m pe r a t u r e A video is played in class to demonstrate the concept.

Dislo cat io n V id eo s!

h t t p : / / w w w . n u m o d is . f r / t r id is / T E M / m e c h an is m s / m u lt ip lic a t io n . h t m l

D islo c a t io n so u r c e s a n d p ile u p in Ge A video is played in class to demonstrate the concept.

Dislo cat io n V id eo s!

h t t p : / / w w w . n u m o d is . f r / t r id is / T E M / m e c h an is m s / m u lt ip lic a t io n . h t m l

D islo c a t io n so u r c e s in S i A video is played in class to demonstrate the concept.

F o r ces Bet w een E d g e Dislo cat io n s

W a s , p . 289 - 290

X & Y forc e s , no Z - forc e Pe a c h - K o hl e r E qua t i o n B ur g er s v ec t o r o f d is lo c a tio n ( 2 )

t r a nspo sed

L i ne v ec t o r o f

d is lo c a tio n ( 2 ) t r a nspo sed

F or c e v e c t or on d is lo c a tio n ( 2 )

S t r ess t enso r i nduc ed b y d is lo c a tio n ( 1 )

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All T o g et h er : L o o p s, M o vem en t , P ileu p

D isl o c a t io n s m o v in g & p il in g up i n I nc o ne l 617 (N i - ba s e d a l l o y) unde r in - si tu s t r a i ni ng i n t h e TE M

h t tp: / / y o utu.be / r - g e D w E8 Z5 Y

A video is played in class to demonstrate the concept.

G r ain Bo u n d ar ies ( 2D)

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htt p : / / w w w - h r em. ms m. c a m. a c . u k / g a l l er y /

R e gi ons of di f fe re nt o r ie n ta tio n

May al so b e d i f f er en t c ry s ta l s tru c tu re

T E M i mag e o f a g r ai n b o u n d ar y i n p u r e Al

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G Bs can b e L in es o f Dislo cat io n s

Dislocation structure in low angle grain boundary http://4.bp.blogspot.com/_52ad6YS2zrs/TEtvk7xnsII/AAAAAAAAAJI/s3G-GLHWfbA/s400/4.jpg

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T i l t g r ai n b o u n d ar y i n Al

h t tp: / / w w w . tf .uni - k i e l .de / m a tw i s / a m a t / de f _ e n/ k a p_ 7/ ba c k bo ne / r 7_ 2_ 1.h t m l

This image is in the public domain. h t tp: / / m o i s e s pi ne da c a f .bl o g s po t.c o m /

T w in n in g

A lte r n a te p la s tic d e f o r m a tio n m e c h a n ism

http://dcg.materials.drexel.edu/wp-content/images/research/nuclear/nuc_research2.jpg http://4.bp.blogspot.com/_52ad6YS2zrs/TEtup9IHG4I/AAAAAAAAAI4/YKSFWTenPDE/s400/1.jpg

h t tp: / / m o i s e s pi ne da c a f .bl o g s po t.c o m / h t tp: / / dc g .m a t e r i a l s .dr e x e l .e du/ ? pa g e _ i d= 14# nuc l e a r

T w i n n i n g o b s e r v e d i n i r r ad i a t e d r ea c t o r pr essur e v essel s t eel

Courtesy of Dynamic Characterization Group, property of Drexel University. Used with permission.

h t tp: / / dc g .m a t e r i a l s .dr e x e l .e du/ ? pa g e _ i d= 14# nuc l e a r

T wi nni ng

Dif f e r e n tly o rie n t e d d is lo c a tio n s i nsi de/ o ut si de t w i n bo unda r y !

Courtesy of Dynamic Characterization Group, property of Drexel University. Used with permission.

In clu sio n s ( 3D)

O t he r pha s e s t ra ppe d w ith in b a s e m a te r ia l

Ex am p l es :

S econda r y p ar t i cl e preci pit at es i n Z irc a loys

C ar bide s i n s t eel s

Y 2 O 3 pa r t i cl es i n O xide D i s pe r s i on S t r e ngt he ne d

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(O D S ) s te e ls S i ngl e c r y s ta l o f Mn S , spa c e gr o up Fm 3 m , F C C c r y s t a l s tru c tu r e

em bedded i n A l ca t o r r ot or s t e e l

Co h er en t vs. In co h er en t

http://i.imgur.com/N42HD.jpg

W hi c h do y ou t hi nk w oul d be bet t e r a t s i nki ng defe c t s ? S t oppi ng di s l oc a t i ons ?

In c o h e r e n t i n c l u s i o n C o h e r e n t i n cl u s i o n

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S w it ch in g G ear s: S t r u ct u r al M at er ial P r o p er t ies

G o a ls:

U n d er st an d t r u e v s. en g i n eer i n g st r ess & st r ai n

Q ua nt i f y a nd di f f e r e nt i a t e be t w e e n ha r dne s s , t oughne s s , s t r e ngt h, duc t i l i t y , s t i f f ne s s

K now how t o m e a s ur e t he s e pr ope r t i e s

R eso l v e st r esses o n t o sl i p sy st em s

P r ed i ct t h e d i f f er en ces i n m ech an i cal r esp o n se b et w een s i ngl e , dua l , a nd pol yc r ys t a l l i ne m a t e r i a l s

Imag e s f r o m n o w o n ar e f r o m T . H . C o u r t n e y , M e c hani c al B e h a v i o r o f M a t e ri a l s unl ess o t her w i se no t ed

f e e l?

Reso lved Sh ear S t r ess

H o w m u c h sh e a r d o e s t h e slip s y s t e

C onsi de r a s i ngl e c ryst a l ba r of FC C m a t e ri a l , t e ns i one d i n t he [ 001] di re c t i on:

m f e e l?

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Reso lved Sh ear S t r ess

h t tp : / / w w w . d o itp o m s . a c . u k/ tlp lib / s lip / p rin t a ll. p h p

P r o ject f o r ce o n to t h e tilted p lan e c o n tain in g th e s lip sy stem ,

to g et

th e

str ess

𝐹

𝜎 𝑠𝑙 𝑖𝑝 = 𝐴

𝐹

= 𝐴 0 = 𝜎 c os 𝜃𝜃

𝑠 𝑙 𝑖𝑝

c os 𝜃𝜃

A lso p ro j e c t s h ear d ir ectio n o f s lip

m o v em en t i n

𝜏 =

𝜎 c os 𝜆

Courtesy of University of Cambridge. Used with permission.

Reso lved Sh ear S t r ess

T h e to ta l s h e a r s tr e s s b e c o m e s :

𝜎

𝜏 =

𝜎 cos 𝜆

cos 𝜃𝜃 =

𝑚

𝑚 =

1

cos 𝜆 cos 𝜃𝜃

Sc h mi d fa c t o r

E f f e c tiv e ly r e d u c e s a p p lie s str e s s f e lt o n a s lip p la n e

Reso lved Sh ear S t r ess

C onsi de r a s i ngl e c ryst a l ba r of FC C m a t e ri a l , t e ns i one d i n t he [ 001] di re c t i on:

H o w m uc h s he a r do e s t he s l i p s y s t e m f e e l ?

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E xam p les o f S h ear & S lip

A l cat o r C - M od rot or s t e e l i n uni a xi a l t e ns i on:

Axis o f t e n sio n

Axis o f t e n sio n

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E vid en ce o f S lip S yst em s

h t tp : / / w w w . d o itp o m s . a c . u k/ tlp lib / s lip / p rin t a ll. p h p

Courtesy of University of Cambridge. Used with permission.

E vid en ce o f S lip S yst em s

h t t p : //w w w .d o i t p o ms .ac .u k /t l p l i b /mi l l e r _ i n d i c e s /p r i n t al l .p h p

A scanning electron micrograph of a single crystal of cadmium

Courtesy of University of Cambridge. Used with permission.

A s c an n i n g e l e c t r o n mi c r o g r ap h o f a s i n g l e c r y s t al o f c ad mi u m d e f o r mi n g b y d i s l o c a t i o n s l i p o n 1 0 0 p l an e s , f o r mi n g s t e p s o n t h e s u r f ac e

E vid en ce o f S lip S yst em s

N. Fr i e d man e t al . P h y s . R e v . L e tt . 109, 095507 ( 2012)

Figure 1

N a nopi l l a r c om pr e s s i on t e s t s us i ng a di a m ond f l a t punc h

C l ear 4 5 d eg r ee an g l es obs e r ve d

S l i p sy st em s a c t i va t e d by s he ar

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E vid en ce o f S lip S yst em s

S. B r i n c k man n e t al . P h y s . R e v . L e tt . 100, 155502 ( 2008)

Figure 1

N a nopi l l a r c om pr e s s i on t e s t s us i ng a di a m ond f l a t punc h

C l ear 4 5 d eg r ee an g l es obs e r ve d

S l i p sy st em s a c t i va t e d by s he ar

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Reso lved Sh ear S t r ess

C onsi de r a s i ngl e c ryst a l ba r of SC m a t e ri a l , t e ns i one d i n t he [ 001] di re c t i on:

H o w m uc h s he a r do e s t he s l i p s y s t e m f e e l ?

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Reso lved Sh ear S t r ess

C onsi de r a s i ngl e c ryst a l ba r of SC m a t e ri a l , t e ns i one d i n t he [ 001] di re c t i on:

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Reso lved Sh ear S t r ess

C onsi de r a s i ngl e c ryst a l ba r of SC m a t e ri a l , t e ns i one d i n t he [ 0 1 1] di re c t i on:

m f e e l?

H o w m u c h sh e a r d o e s t h e slip s y s t e f e e l?

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W ill It S lip o r Br eak?

Bal an ce b et w een t w o m ech an i s m s :

𝝉 𝑐 𝑟 𝑖𝑡 𝑖 𝑐 𝑎 𝑙 > 𝝈 𝑐𝑜 𝑠 𝝀𝝀 𝑐𝑜 𝑠 𝜽𝜽

v s.

𝝈 > 𝝈 𝑈 𝑇 𝑆

B o n d b r e ak i n g

Cr it ical Reso lved Sh ear S t r ess ( τ CRS S )

S h e a r s tr e ss th a t is e n o u g h to g e t d is lo c a tio n s m ovi ng (pl a s t i c de form a t i on)

Rel at ed t o th e y ie ld s t r e ss ( σ y ) , th e str e s s w h e r e p la s tic d e f o r m a tio n s ta r ts :

𝜎 𝑦

= 𝑚 𝜏 𝐶 𝑅 𝑆 𝑆

NOT E : σ y ha s c rys t a l l ogra phi c

de pe nde nc e i n s i ngl e

c rys t a l s! W ha t a bout pol yc rys t a l s ?

τ CRS S

vs. T em p er at u r e

T he r m a l e ne r g y so lo w , t h a t sm a ll ba r r i e r s be c o m e in su r m o u n t a b le

C o mmo n l y c i t e d ma t e r i a l pr o pe r t y r e g i o n

D if f u sio n - e nha nc e d r e g i o n ( e a s i e r t o m ov e d islo c a t i o n s )

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Wha t H a ppe ns Whe n Dislo cat io n s G et S t u ck?

C r o s s slip : sw itc h in g to o th e r slip p la n e s

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R e s ol ve d s he a r st re ss m us t be hi gh e nough!

S t r ess vs. S t r ain

St re ss: Forc e ove r a re a

E ngi ne e ri n g st re ss : Forc e di vi de d by ori gi nal ar ea

T r u e str e ss : Forc e di vi de d by ac t ual ar ea as i t

c hange s

𝜎 =

𝐹

𝐴 0

𝜎 𝑡

𝐹

=

𝐴 ( 𝑡 )

𝐹

=

𝐴 0

𝐴 0

𝐴 ( 𝑡 )

= 𝜎 𝐴 0

𝐴 ( 𝑡 )

C onse rve

vol um e duri ng

s t re t c hi ng:

V 0 = V ( t )

S t r ess vs. S t r ain

𝐹

𝜎 =

𝐴 0

𝜎 𝑡

𝐹 𝐹

= =

𝐴 ( 𝑡 ) 𝐴 0

𝐴 0

𝐴 ( 𝑡 )

= 𝜎

𝐴 0

𝐴 ( 𝑡 )

𝑡

𝑡

C onse rve

vol um e duri ng

s t re t c hi ng: V 0

= V ( t )

𝑉 = 𝐴 𝐿

= 𝑉

= 𝐴

𝐿

𝐴 ( 𝑡 )

𝑡

; =

𝐿 0

0 0 0

𝐴 0

𝐿 ( 𝑡 )

𝜎 𝑡

= 𝜎 𝐴 0

𝐴 ( 𝑡 )

= 𝜎

𝐿 ( 𝑇 )

𝐿 0

= 𝜎

𝐿 0

+ 𝛿𝛿 𝐿

= 𝜎

𝛿𝛿 𝐿

1 +

𝐿 0

𝐿 0

E ng i ne e r i n g s t r a i n ( ε )

T r u e vs. E n g in eer in g S t r ain

E ngi ne e ri ng st ra i n ( ε ): 𝛿𝛿𝐿

𝐿 0

(from ori gi nal l e ngt h)

T ru e st ra i n ( ε T ):

Inst a nt a ne ous

i nc re a s e

i n l e ngt h:

𝜀𝜀 𝑇

𝐿 ( 𝑡 )

=

𝐿 0

𝑑 𝐿

𝐿 0 + 𝛿𝛿 𝐿

𝐿 0

𝐿

= ln 𝐿 ( 𝑡 )

ln 𝐿 0

𝐿 𝑡

𝐿 0

= ln

𝜀𝜀 𝑇

= ln

= ln 1 + 𝜀𝜀

S t r ess- S t r ain Cu r ves

h t t p : / / k e y t o m e t a l s .c o m / p a g e .a s p x ?ID =C h e c k A r t i c l e & s i t e =k t s & N M=4 2

http://keytometals.com/img/screens/stress_strain_comparison.gif

Courtesy of 2015 Key to Metals AG. Used with permission.

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S in g le, Du al, an d P o lycr yst als

D i s l oc a t i on pi l e up, pi nni ng

s l i p sy s te m

Pr im ar y

s l i p sy s te m

P r i m a r y s l i p s y s t e m

S e c o nda r y s l i p s y s t e m

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M easu r in g S t r ess -S tr a i n

J . M . Ger e, “M ec ha ni c s o f M a t er i a l s , pp. 1 2 , 1 4

U n ia x ial t e n s ile t e s t e r , w it h U n ia x ial c o m p r e s s io n t e s t e r , w it h e x t e n so me t e r f o r me a su r i n g s tr a i n e x t e n so me t e r a n d d i a me t e r me a su r e me n t

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Dislo cat io n s an d Def ect s

E . B it z ek a nd P. G u m bs ch , Dy na m i c a s pec t s of d i s l oc a t i on m ot i on : a t om i s t i c s i m ul a t i o ns , M a t er i a l s S ci ence a nd E ng i neer i ng A , 4 0 0 - 401 ( 2005) , pp. 4 0 - 44

D e fe c t s c a n sl ow dow n (pi n) di sl oc a t i on s

A video is played in class to demonstrate the concept.

Review in g M at er ial P r o p er t ies

Fi nd t he fol l ow i ng on a st re s s - stra i n di a gra m :

T oughne s s

St re ngt h

D u c tility

S tif f n e ss

Pe rha ps de fi ne t he m fi rs t

Y oung's M odul us (S ti ffne s s , E )

Measu r es el ast i c de f or m a t i on vs . s t r e s s

So u r ce: W ik im ed i a C o m m o n s

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T oughne s s ( G c )

M eas u r es t h e en er g y i t t ak es t o s ep ar at e a m at er i al

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M at er ial P r o p er t ies o n S t r ess- S t r ain Diag r am

[Stress-Strain Curve]

Courtesy of Ben Best .Used with permission.

Courtesy of Ben Best . Used with permission.

h t t p : / / w w w .b e n b e s t .c o m / c r y o n i c s / l e s s o n s .h t m l

M at er ials Select io n Ch ar t s

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h ttp ://w w w - g .e ng .c a m . a c .uk/ 125/ now / m f s / t ut o r i a l / non_ I E / c ha r t s .ht m l

F ailu r e Cr it er ia Cr ack P r opa ga ti on

R esi st an ce t o cr ack pr opa ga t i on

-Y 1 , Y 2 ar e g eom et r i c f act ors ne ar 1

* , F * ar e cr i t i ca l st r ess and f orce, r espe ct i ve l y

So u r ce: in v en to r . g r an tad es ig n . co m © source unknown . All rights reserved. This content is

excluded from our Creative Commons license. For more information, see http://ocw.mit.edu/help/faq-fair-use/ .

F r act u r e T o u g h n ess Real D a ta fr om A l c a tor C -M od

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E n g in e e r in g M a t e r ia ls Sc ie n c e , Mi l t on O hri ng , Ch . 10

F ailu r e Cr it er ia F at ig u e

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Rep eat ed ap p l i cat i o n of str e s s c a n cau s e c ra c ks t o grow

Induc e d by vi bra t i ons, m ech an i cal l o ad i n g

T e llta le f a tig u e str ia tio n s

Commons license. For more information, see http://ocw.mit.edu/help/faq-fair- use/ . W he r e do the s e

S our c e : w w w .s v .vt .e du/ c l a s s e s / M S E 2094_N ot e B ook/ 97C l a s s P r oj / a na l / ke l l y / f a t i g u e .ht m l c om e fr om ?

F ailu r e Cr it er ia F at ig u e

St re ss (S) vs . num be r of c yc l e s ( N)

L o w e r lim it o f s tr e s s (w he re N is i nfi ni t e ) i s t h e s af e zo n e

W hy do the se

This image is in the public domain. lim it s e x ist ?

S our c e : w w w .nd e - e d.or g / E duc a t i onR e s our c e s / C om m uni t y C ol l e ge / M a t e r i a l s / M e c h a ni c a l / S - N F at i g u e. h t m

F at ig u e St r iat io n s in Alcat o r C- M o d Ro t o r

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F ailu r e M ech an ism s in T en sio n

1. 1.

2. 2.

3. 3.

4.

4.

1 1. B r i t tl e f r a c tu r e

2 2 . . S in g le c r y s t a l slip b a n d s

3 3 . . I de a l duc t i l e f r a c t ur e ( f ul l

4 e l o ng a t i o n)

4. R e a lis t ic c u p - a n d - c o n e

f r a c tu r e

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S t a g e s o f c u p - a n d - c o n e f r a c tu r e f o r ma ti o n i n d u c t ile m a t e r ia ls

D ef ect s , S l i de 81

22. 14 : N uc l e a r M a t e ri a l s E n g in e e r in g M a t e r ia ls Sc ie n c e , Mi lt on O hri ng , Ch . 10

E xam p les o f Cu p - an d- Co n e F r act u r e in Alcat o r C- M o d

Br it t le & Du ct ile F r act u r e, S id e b y S id e

Mn S Pr e c ip it a t e

D u c t ile

B r i t tl e

[Stress-Strain Curve]
http://www.nationalboard.org/images/site_img/large/creep_figure1_2.jpg

Cr eep P last ic Def o r m at io n Belo w Y ield S t r ess

I m a g in e s tr e tc h in g a b a r o f m e ta l w ith in th e e la stic re gi on

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h t t p : / / w w w .n a t i o n a l b o a r d .o r g / In d e x .a s p x ? p a g e ID =1 8 1

Cr eep S t r ess vs. T im e

J . M . Ger e, “M ec ha ni c s o f M a t er i a l s , pp. 2 2

St re ss inc re a se d e la stic a lly to σ 0

H e l d for l ong t i m e

S tr e s s a t c o n sta n t s t r ai n d ecr eas es d u e to cr eep

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Cr eep M ech an ism s

This image is in the public domain.

So u r ce: W ik im ed i a C o m m o n s

Pl a s t i c fl ow unde r c o n s ta n t s tr e ss

T e ns i on, gra vi t y . . .

H a ppe ns w e l l be l ow y ie ld str e s s

M u ltip le m o d e s (C obl e , N a ba rro - He r r i n g ...)

Cr eep M ech an ism s

D islo c a tio n c lim b

F ol l ow s pow e r l a w

N a ba rro - H e rri ng (dif fusi ona l )

V acanc y m ove m ent

C obl e

G r a i n bounda r y m ove m e nt

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E n g in e e r in g M a t e r ia ls Sc ie n c e , Mi l t on O hri ng , Ch . 10

F ailu r e Cr it er io n Cr eep Li fe ti me

C re e p rupture lif e tim e c a n lim it use ful ne s s of pa rt

E x a m p le : A llo y s H T 9, T 91 i n hi gh t em p er at u r e s er v i ce c ondi t i ons

Courtesy of Elsevier, Inc., http://www.sciencedirect.com . Used with permission. Source: Klueh, R. L., and A. T. Nelson. " Ferritic / Martensitic Steels for Next-generation Reactors ." Journal of Nuclear Materials 371, no. 1-3 (2007): 37-52.

S our c e : R .L . K l ue h, A .T . N e l s on. J . N uc l . M at e r . , 371( 1- 3) : 37- 52 ( 2007) .

Cr eep F ailu r e b y T im e at T em p er at u r e an d Pr essu r e

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Cr eep f a i l ur e o f a l l o y T9 1 due t o i m pr o per hea t t r ea t m e n t , hea t e d a bo v e A1 t em per a t ur e . I n T . T o t enm e i e r , “E x per i ence w i t h G r a de 9 1 S t eel i n t he F o s s i l

Po w e r I ndus t r y . P r es en t a t i o n, AL S T O M , F eb. 2 0 0 9 .

MIT OpenCourseWare http://ocw.mit.edu

22.14 Materials in Nuclear Engineering

Spring 2015

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